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DOE OSTI · 1667265

Materials Data on MoP3 by Materials Project

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Abstract

MoP3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Mo6+ is bonded in a distorted body-centered cubic geometry to fourteen P2- atoms. There are eight shorter (2.63 Å) and six longer (3.03 Å) Mo–P bond lengths. There are two inequivalent P2- sites. In the first P2- site, P2- is bonded in a body-centered cubic geometry to four equivalent Mo6+ and four equivalent P2- atoms. All P–P bond lengths are 2.63 Å. In the second P2- site, P2- is bonded in a distorted body-centered cubic geometry to six equivalent Mo6+ and eight equivalent P2- atoms.

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36 MATERIALS SCIENCEcrystal structureMo-PMoP3

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2020-07-23. Materials Data on MoP3 by Materials Project. https://doi.org/10.17188/1667265

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