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DOE OSTI · 1674736

Materials Data on Al(NF2)3 by Materials Project

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Abstract

AlNF6N2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight ammonia molecules and one AlNF6 framework. In the AlNF6 framework, Al3+ is bonded to six equivalent F1- atoms to form AlF6 octahedra that share corners with six equivalent NF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Al–F bond lengths are 1.86 Å. N1+ is bonded to six equivalent F1- atoms to form NF6 octahedra that share corners with six equivalent AlF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All N–F bond lengths are 1.92 Å. F1- is bonded in a linear geometry to one Al3+ and one N1+ atom.

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36 MATERIALS SCIENCEAl(NF2)3Al-F-Ncrystal structure

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2020-05-03. Materials Data on Al(NF2)3 by Materials Project. https://doi.org/10.17188/1674736

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