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DOE OSTI · 1675564

Materials Data on Na2AgSbCl6 by Materials Project

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Abstract

(Na)2AgSbCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight natrium molecules and one AgSbCl6 framework. In the AgSbCl6 framework, Ag1+ is bonded to six equivalent Cl1- atoms to form AgCl6 octahedra that share corners with six equivalent SbCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ag–Cl bond lengths are 2.68 Å. Sb3+ is bonded to six equivalent Cl1- atoms to form SbCl6 octahedra that share corners with six equivalent AgCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Sb–Cl bond lengths are 2.65 Å. Cl1- is bonded in a linear geometry to one Ag1+ and one Sb3+ atom.

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36 MATERIALS SCIENCEAg-Cl-Na-Sbcrystal structureNa2AgSbCl6

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2020-05-04. Materials Data on Na2AgSbCl6 by Materials Project. https://doi.org/10.17188/1675564

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