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DOE OSTI · 1676772

Materials Data on PPtN5ClO6 by Materials Project

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Abstract

PtNPO3N2ON2ClO2 crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules; two hydroxylamine, o-amino- molecules; two phosphonic acid molecules; two N2Cl clusters; and two PtN clusters. In each N2Cl cluster, N+0.60+ is bonded in a single-bond geometry to one Cl1- atom. The N–Cl bond length is 1.65 Å. Cl1- is bonded in an L-shaped geometry to two equivalent N+0.60+ atoms. In each PtN cluster, Pt5+ is bonded in a distorted single-bond geometry to one N+0.60+ atom. The Pt–N bond length is 1.75 Å. N+0.60+ is bonded in a distorted single-bond geometry to one Pt5+ atom.

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36 MATERIALS SCIENCECl-N-O-P-Ptcrystal structurePPtN5ClO6

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2020-04-29. Materials Data on PPtN5ClO6 by Materials Project. https://doi.org/10.17188/1676772

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36 MATERIALS SCIENCE↗