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DOE OSTI · 1677259

Materials Data on Rb2O by Materials Project

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Abstract

Rb2O is Hydrophilite structured and crystallizes in the monoclinic P2_1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.81–2.92 Å. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.81–2.93 Å. O2- is bonded to six Rb1+ atoms to form a mixture of edge and corner-sharing ORb6 octahedra. The corner-sharing octahedra tilt angles range from 53–55°.

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36 MATERIALS SCIENCEcrystal structureO-RbRb2O

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2020-05-02. Materials Data on Rb2O by Materials Project. https://doi.org/10.17188/1677259

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