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DOE OSTI · 1679917

Materials Data on Ce(Sb3Ru)4 by Materials Project

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Abstract

CeRu4Sb12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Ce3+ is bonded to twelve equivalent Sb1- atoms to form CeSb12 cuboctahedra that share faces with eight equivalent RuSb6 octahedra. All Ce–Sb bond lengths are 3.50 Å. Ru+2.25+ is bonded to six equivalent Sb1- atoms to form RuSb6 octahedra that share corners with six equivalent RuSb6 octahedra and faces with two equivalent CeSb12 cuboctahedra. The corner-sharing octahedral tilt angles are 54°. All Ru–Sb bond lengths are 2.63 Å. Sb1- is bonded in a 2-coordinate geometry to one Ce3+, two equivalent Ru+2.25+, and two equivalent Sb1- atoms. There are one shorter (2.96 Å) and one longer (3.03 Å) Sb–Sb bond lengths.

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36 MATERIALS SCIENCECe(Sb3Ru)4Ce-Ru-Sbcrystal structure

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2020-05-02. Materials Data on Ce(Sb3Ru)4 by Materials Project. https://doi.org/10.17188/1679917

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