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DOE OSTI · 1680146

Materials Data on Ni(ClO)2 by Materials Project

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Abstract

Ni(OCl)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two Ni(OCl)2 ribbons oriented in the (0, 1, 0) direction. Ni is bonded to two equivalent O and four Cl atoms to form distorted edge-sharing NiCl4O2 octahedra. Both Ni–O bond lengths are 1.78 Å. There are two shorter (2.31 Å) and two longer (2.38 Å) Ni–Cl bond lengths. O is bonded in a single-bond geometry to one Ni atom. There are two inequivalent Cl sites. In the first Cl site, Cl is bonded in an L-shaped geometry to two equivalent Ni atoms. In the second Cl site, Cl is bonded in an L-shaped geometry to two equivalent Ni atoms.

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36 MATERIALS SCIENCECl-Ni-Ocrystal structureNi(ClO)2

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2020-05-05. Materials Data on Ni(ClO)2 by Materials Project. https://doi.org/10.17188/1680146

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