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DOE OSTI · 1692733

Materials Data on PdS(NO)3 by Materials Project

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Abstract

PdN3SO3 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four PdN3 clusters. In each PdN3 cluster, Pd2+ is bonded in a distorted trigonal non-coplanar geometry to three N2+ atoms. There are a spread of Pd–N bond distances ranging from 1.76–1.91 Å. There are three inequivalent N2+ sites. In the first N2+ site, N2+ is bonded in a single-bond geometry to one Pd2+ atom. In the second N2+ site, N2+ is bonded in a single-bond geometry to one Pd2+ atom. In the third N2+ site, N2+ is bonded in a single-bond geometry to one Pd2+ atom.

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36 MATERIALS SCIENCEcrystal structureN-O-Pd-SPdS(NO)3

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2020-04-30. Materials Data on PdS(NO)3 by Materials Project. https://doi.org/10.17188/1692733

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DOE OSTI2026

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