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DOE OSTI · 1695802

Materials Data on Zn2Cl5O2 by Materials Project

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Abstract

Zn2Cl5O2 crystallizes in the orthorhombic Fdd2 space group. The structure is three-dimensional and consists of eight oxygen molecules and one Zn2Cl5 framework. In the Zn2Cl5 framework, Zn is bonded to four Cl atoms to form corner-sharing ZnCl4 tetrahedra. There are a spread of Zn–Cl bond distances ranging from 2.25–2.32 Å. There are three inequivalent Cl sites. In the first Cl site, Cl is bonded in a water-like geometry to two equivalent Zn atoms. In the second Cl site, Cl is bonded in a single-bond geometry to one Zn atom. In the third Cl site, Cl is bonded in a water-like geometry to two equivalent Zn atoms.

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36 MATERIALS SCIENCECl-O-Zncrystal structureZn2Cl5O2

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2020-05-02. Materials Data on Zn2Cl5O2 by Materials Project. https://doi.org/10.17188/1695802

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