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DOE OSTI · 1696161

Materials Data on AgH3BrN by Materials Project

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Abstract

AgNH3Br crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two AgNH3Br clusters. Ag1+ is bonded in a 2-coordinate geometry to one N3- and one Br1- atom. The Ag–N bond length is 2.20 Å. The Ag–Br bond length is 2.53 Å. N3- is bonded in a distorted trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. Br1- is bonded in a 1-coordinate geometry to one Ag1+ atom.

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36 MATERIALS SCIENCEAg-Br-H-NAgH3BrNcrystal structure

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2020-05-03. Materials Data on AgH3BrN by Materials Project. https://doi.org/10.17188/1696161

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