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DOE OSTI · 1697279

Materials Data on Na2NbAgF6 by Materials Project

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Abstract

(Na)2AgNbF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight sodium molecules and one AgNbF6 framework. In the AgNbF6 framework, Nb3+ is bonded to six equivalent F1- atoms to form NbF6 octahedra that share corners with six equivalent AgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Nb–F bond lengths are 2.07 Å. Ag1+ is bonded to six equivalent F1- atoms to form AgF6 octahedra that share corners with six equivalent NbF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ag–F bond lengths are 2.41 Å. F1- is bonded in a linear geometry to one Nb3+ and one Ag1+ atom.

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36 MATERIALS SCIENCEAg-F-Na-Nbcrystal structureNa2NbAgF6

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2020-05-04. Materials Data on Na2NbAgF6 by Materials Project. https://doi.org/10.17188/1697279

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