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DOE OSTI · 1698493

Materials Data on Cr(ClO2)2 by Materials Project

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Abstract

Cr(O2Cl)2 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two Cr(O2Cl)2 ribbons oriented in the (1, 0, 0) direction. Cr is bonded in a distorted octahedral geometry to four O and two equivalent Cl atoms. There is two shorter (1.67 Å) and two longer (1.90 Å) Cr–O bond length. Both Cr–Cl bond lengths are 2.48 Å. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one Cr and one Cl atom. The O–Cl bond length is 1.66 Å. In the second O site, O is bonded in a single-bond geometry to one Cr atom. Cl is bonded in a water-like geometry to one Cr and one O atom.

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36 MATERIALS SCIENCECl-Cr-OCr(ClO2)2crystal structure

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2020-05-03. Materials Data on Cr(ClO2)2 by Materials Project. https://doi.org/10.17188/1698493

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