Materials Data on Ce2In2PdRh by Materials Project

Abstract

Ce2RhPdIn2 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are six inequivalent Ce sites. In the first Ce site, Ce is bonded in a 11-coordinate geometry to one Rh, four Pd, and six In atoms. The Ce–Rh bond length is 3.16 Å. There are two shorter (3.07 Å) and two longer (3.09 Å) Ce–Pd bond lengths. There are a spread of Ce–In bond distances ranging from 3.33–3.41 Å. In the second Ce site, Ce is bonded in a 11-coordinate geometry to three Rh, two equivalent Pd, and six In atoms. There are two shorter (3.02 Å) and one longer (3.19 Å) Ce–Rh bond lengths. Both Ce–Pd bond lengths are 3.13 Å. There are a spread of Ce–In bond distances ranging from 3.31–3.44 Å. In the third Ce site, Ce is bonded in a 11-coordinate geometry to one Rh, four Pd, and six In atoms. The Ce–Rh bond length is 3.07 Å. There are two shorter (3.09 Å) and two longer (3.11 Å) Ce–Pd bond lengths. There are a spread of Ce–In bond distances ranging from 3.33–3.41 Å. In the fourth Ce site, Ce is bonded in a 11-coordinate geometry to three Rh, two equivalent Pd, and six In atoms. There are two shorter (3.05 Å) and one longer (3.09 Å) Ce–Rh bond lengths. Both Ce–Pd bond lengths are 3.14 Å. There are a spread of Ce–In bond distances ranging from 3.31–3.45 Å. In the fifth Ce site, Ce is bonded in a 11-coordinate geometry to one Rh, four Pd, and six In atoms. The Ce–Rh bond length is 3.06 Å. All Ce–Pd bond lengths are 3.10 Å. There are a spread of Ce–In bond distances ranging from 3.33–3.42 Å. In the sixth Ce site, Ce is bonded in a 11-coordinate geometry to three Rh, two equivalent Pd, and six In atoms. There are two shorter (3.03 Å) and one longer (3.09 Å) Ce–Rh bond lengths. Both Ce–Pd bond lengths are 3.16 Å. There are a spread of Ce–In bond distances ranging from 3.31–3.42 Å. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a 9-coordinate geometry to six Ce and three In atoms. There are a spread of Rh–In bond distances ranging from 2.89–2.93 Å. In the second Rh site, Rh is bonded in a 9-coordinate geometry to three Ce and six In atoms. There are a spread of Rh–In bond distances ranging from 2.79–2.81 Å. In the third Rh site, Rh is bonded in a 9-coordinate geometry to three Ce and six In atoms. There are two shorter (2.80 Å) and four longer (2.81 Å) Rh–In bond lengths. There are three inequivalent Pd sites. In the first Pd site, Pd is bonded in a 9-coordinate geometry to six Ce and three In atoms. There are two shorter (2.91 Å) and one longer (2.92 Å) Pd–In bond lengths. In the second Pd site, Pd is bonded in a 9-coordinate geometry to six Ce and three In atoms. There are a spread of Pd–In bond distances ranging from 2.89–2.92 Å. In the third Pd site, Pd is bonded in a 9-coordinate geometry to six Ce and three In atoms. There are two shorter (2.92 Å) and one longer (2.93 Å) Pd–In bond lengths. There are six inequivalent In sites. In the first In site, In is bonded in a 4-coordinate geometry to six Ce, two equivalent Rh, and two Pd atoms. In the second In site, In is bonded in a 10-coordinate geometry to six Ce, three Rh, and one Pd atom. In the third In site, In is bonded in a 4-coordinate geometry to six Ce, two equivalent Rh, and two Pd atoms. In the fourth In site, In is bonded in a 4-coordinate geometry to six Ce, three Rh, and one Pd atom. In the fifth In site, In is bonded in a 4-coordinate geometry to six Ce, two equivalent Rh, and two Pd atoms. In the sixth In site, In is bonded in a 4-coordinate geometry to six Ce, three Rh, and one Pd atom.