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DOE OSTI · 1708076

Materials Data on RbSrCl3 by Materials Project

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Abstract

RbSrCl3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent Cl1- atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent RbCl12 cuboctahedra, faces with six equivalent RbCl12 cuboctahedra, and faces with eight equivalent SrCl6 octahedra. All Rb–Cl bond lengths are 4.03 Å. Sr2+ is bonded to six equivalent Cl1- atoms to form SrCl6 octahedra that share corners with six equivalent SrCl6 octahedra and faces with eight equivalent RbCl12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Sr–Cl bond lengths are 2.85 Å. Cl1- is bonded in a linear geometry to four equivalent Rb1+ and two equivalent Sr2+ atoms.

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36 MATERIALS SCIENCECl-Rb-Srcrystal structureRbSrCl3

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2020-05-05. Materials Data on RbSrCl3 by Materials Project. https://doi.org/10.17188/1708076

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