Materials Data on VPbO4 by Materials Project

Abstract

VPbO4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. V4+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of V–O bond distances ranging from 1.73–1.76 Å. Pb4+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Pb–O bond distances ranging from 2.39–2.67 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one V4+ and two equivalent Pb4+ atoms. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one V4+ and two equivalent Pb4+ atoms. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one V4+ and two equivalent Pb4+ atoms. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to one V4+ and two equivalent Pb4+ atoms.