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DOE OSTI · 1708363

Materials Data on NClO4 by Materials Project

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Abstract

NClO4 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of four NClO4 ribbons oriented in the (1, 0, 0) direction. N is bonded in a bent 150 degrees geometry to two equivalent O atoms. Both N–O bond lengths are 1.82 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.42 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.43 Å. In the third O site, O is bonded in a bent 120 degrees geometry to one N and one Cl atom. The O–Cl bond length is 1.54 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

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36 MATERIALS SCIENCECl-N-Ocrystal structureNClO4

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2020-05-02. Materials Data on NClO4 by Materials Project. https://doi.org/10.17188/1708363

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