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DOE OSTI · 1708695

Materials Data on Sb(Cl3O)2 by Materials Project

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Abstract

Sb(OCl3)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb(OCl3)2 clusters. Sb is bonded in an octahedral geometry to six Cl atoms. There are a spread of Sb–Cl bond distances ranging from 2.39–2.48 Å. O is bonded in a distorted single-bond geometry to one Cl atom. The O–Cl bond length is 2.40 Å. There are three inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the second Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the third Cl site, Cl is bonded in a distorted bent 120 degrees geometry to one Sb and one O atom.

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36 MATERIALS SCIENCECl-O-Sbcrystal structureSb(Cl3O)2

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2020-05-02. Materials Data on Sb(Cl3O)2 by Materials Project. https://doi.org/10.17188/1708695

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36 MATERIALS SCIENCE↗