Materials Data on P2H16PbC6(NO3)2 by Materials Project

Abstract

(C3PH8)2Pb(NO3)2 crystallizes in the tetragonal P4_12_12 space group. The structure is three-dimensional and consists of eight trimethylphosphine molecules and one Pb(NO3)2 framework. In the Pb(NO3)2 framework, Pb2+ is bonded in a 2-coordinate geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.65–3.16 Å. N3- is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.26–1.29 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Pb2+ and one N3- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Pb2+ and one N3- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Pb2+ and one N3- atom.