Materials Data on Dy(NO5)3 by Materials Project

Abstract

DyN3O11(O2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four oxygen molecules and two DyN3O11 clusters. In each DyN3O11 cluster, Dy is bonded in a 2-coordinate geometry to one N and seven O atoms. The Dy–N bond length is 2.09 Å. There are a spread of Dy–O bond distances ranging from 1.91–2.97 Å. There are three inequivalent N sites. In the first N site, N is bonded in a 3-coordinate geometry to three O atoms. There are a spread of N–O bond distances ranging from 0.98–1.52 Å. In the second N site, N is bonded in a distorted rectangular see-saw-like geometry to one Dy and three O atoms. There are a spread of N–O bond distances ranging from 0.89–1.78 Å. In the third N site, N is bonded in a distorted trigonal planar geometry to three O atoms. There are a spread of N–O bond distances ranging from 1.25–1.46 Å. There are eleven inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one N atom. In the second O site, O is bonded in a bent 150 degrees geometry to one Dy and one O atom. The O–O bond length is 1.15 Å. In the third O site, O is bonded in a distorted single-bond geometry to one Dy and one N atom. In the fourth O site, O is bonded in a single-bond geometry to one O atom. In the fifth O site, O is bonded in a single-bond geometry to one Dy and one N atom. In the sixth O site, O is bonded in a single-bond geometry to one Dy and one N atom. In the seventh O site, O is bonded in a distorted bent 120 degrees geometry to one Dy and one N atom. In the eighth O site, O is bonded in a single-bond geometry to one N atom. In the ninth O site, O is bonded in a 1-coordinate geometry to one Dy and one N atom. In the tenth O site, O is bonded in a bent 120 degrees geometry to one Dy and one N atom. In the eleventh O site, O is bonded in a single-bond geometry to one N atom.