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DOE OSTI · 1715280

Materials Data on Mn(SbO3)2 by Materials Project

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Abstract

MnSb2O6 is zeta iron carbide-derived structured and crystallizes in the trigonal P-31m space group. The structure is three-dimensional. Mn2+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with twelve equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Mn–O bond lengths are 2.29 Å. Sb5+ is bonded to six equivalent O2- atoms to form SbO6 octahedra that share corners with six equivalent MnO6 octahedra and edges with three equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Sb–O bond lengths are 2.02 Å. O2- is bonded in a distorted trigonal planar geometry to one Mn2+ and two equivalent Sb5+ atoms.

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36 MATERIALS SCIENCEcrystal structureMn(SbO3)2Mn-O-Sb

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2020-05-03. Materials Data on Mn(SbO3)2 by Materials Project. https://doi.org/10.17188/1715280

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