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DOE OSTI · 1717288

Materials Data on GeC4NCl3 by Materials Project

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Abstract

C4NGeCl3 is Ammonia-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four trichlorogermane molecules and four C4N clusters. In each C4N cluster, there are three inequivalent C+0.50+ sites. In the first C+0.50+ site, C+0.50+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.69 Å. In the second C+0.50+ site, C+0.50+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.68 Å. In the third C+0.50+ site, C+0.50+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.55 Å. N3- is bonded in a 4-coordinate geometry to four C+0.50+ atoms.

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36 MATERIALS SCIENCEC-Cl-Ge-Ncrystal structureGeC4NCl3

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2020-04-29. Materials Data on GeC4NCl3 by Materials Project. https://doi.org/10.17188/1717288

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36 MATERIALS SCIENCE↗