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DOE OSTI · 1718687

Materials Data on Fe(ClO2)2 by Materials Project

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Abstract

FeCl2(O)4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Fe is bonded in a distorted square co-planar geometry to four O and two equivalent Cl atoms. There are two shorter (2.03 Å) and two longer (2.09 Å) Fe–O bond lengths. Both Fe–Cl bond lengths are 2.88 Å. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one Fe and one Cl atom. The O–Cl bond length is 1.58 Å. In the second O site, O is bonded in a bent 120 degrees geometry to one Fe and one Cl atom. The O–Cl bond length is 1.58 Å. Cl is bonded in a distorted trigonal non-coplanar geometry to one Fe and two O atoms.

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36 MATERIALS SCIENCECl-Fe-Ocrystal structureFe(ClO2)2

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2020-05-02. Materials Data on Fe(ClO2)2 by Materials Project. https://doi.org/10.17188/1718687

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