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DOE OSTI · 1719553

Materials Data on Cu(SbO2)2 by Materials Project

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Abstract

CuSb2O4 crystallizes in the tetragonal P4_2bc space group. The structure is three-dimensional. Cu2+ is bonded to six O2- atoms to form distorted edge-sharing CuO6 octahedra. There are a spread of Cu–O bond distances ranging from 1.99–2.49 Å. Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. All Sb–O bond lengths are 2.00 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu2+ and one Sb3+ atom. In the second O2- site, O2- is bonded in a trigonal planar geometry to one Cu2+ and two equivalent Sb3+ atoms.

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36 MATERIALS SCIENCEcrystal structureCu(SbO2)2Cu-O-Sb

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2020-05-04. Materials Data on Cu(SbO2)2 by Materials Project. https://doi.org/10.17188/1719553

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