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DOE OSTI · 1719716

Materials Data on PrClO2 by Materials Project

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Abstract

PrO2Cl crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Pr is bonded in a 9-coordinate geometry to six O and three equivalent Cl atoms. There are a spread of Pr–O bond distances ranging from 2.40–2.54 Å. There are two shorter (2.93 Å) and one longer (2.98 Å) Pr–Cl bond lengths. There are two inequivalent O sites. In the first O site, O is bonded in a trigonal planar geometry to three equivalent Pr atoms. In the second O site, O is bonded in a trigonal planar geometry to three equivalent Pr atoms. Cl is bonded in a trigonal non-coplanar geometry to three equivalent Pr atoms.

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36 MATERIALS SCIENCECl-O-Prcrystal structurePrClO2

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2020-04-26. Materials Data on PrClO2 by Materials Project. https://doi.org/10.17188/1719716

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