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DOE OSTI · 1722696

Materials Data on HoPRu2C by Materials Project

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Abstract

HoRu2CP crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Ho3+ is bonded in a 4-coordinate geometry to four equivalent C4- and three equivalent P3- atoms. All Ho–C bond lengths are 2.63 Å. There are one shorter (3.06 Å) and two longer (3.11 Å) Ho–P bond lengths. Ru2+ is bonded in a distorted single-bond geometry to one C4- and three equivalent P3- atoms. The Ru–C bond length is 1.86 Å. There are one shorter (2.42 Å) and two longer (2.46 Å) Ru–P bond lengths. C4- is bonded to four equivalent Ho3+ and two equivalent Ru2+ atoms to form a mixture of corner and edge-sharing CHo4Ru2 octahedra. The corner-sharing octahedral tilt angles are 21°. P3- is bonded in a 9-coordinate geometry to three equivalent Ho3+ and six equivalent Ru2+ atoms.

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36 MATERIALS SCIENCEC-Ho-P-Rucrystal structureHoPRu2C

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2020-05-03. Materials Data on HoPRu2C by Materials Project. https://doi.org/10.17188/1722696

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