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DOE OSTI · 1724767

Materials Data on Th(P3Ru)4 by Materials Project

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Abstract

Th(RuP3)4 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Th4+ is bonded to twelve equivalent P1- atoms to form ThP12 cuboctahedra that share faces with eight equivalent RuP6 octahedra. All Th–P bond lengths are 3.11 Å. Ru2+ is bonded to six equivalent P1- atoms to form RuP6 octahedra that share corners with six equivalent RuP6 octahedra and faces with two equivalent ThP12 cuboctahedra. The corner-sharing octahedral tilt angles are 62°. All Ru–P bond lengths are 2.36 Å. P1- is bonded in a 5-coordinate geometry to one Th4+, two equivalent Ru2+, and two equivalent P1- atoms. There are one shorter (2.33 Å) and one longer (2.34 Å) P–P bond lengths.

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36 MATERIALS SCIENCEcrystal structureP-Ru-ThTh(P3Ru)4

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2020-05-03. Materials Data on Th(P3Ru)4 by Materials Project. https://doi.org/10.17188/1724767

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