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DOE OSTI · 1725356

Materials Data on CoH18Br2N6ClO3 by Materials Project

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Abstract

Co(NH3)6ClO3(Br)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;cobalt molecules, eight hydrobromic acid molecules, and four ClO3 clusters. In each ClO3 cluster, there are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Cl1- atom. The O–Cl bond length is 1.52 Å. In the second O2- site, O2- is bonded in a single-bond geometry to one Cl1- atom. The O–Cl bond length is 1.50 Å. In the third O2- site, O2- is bonded in a single-bond geometry to one Cl1- atom. The O–Cl bond length is 1.50 Å. Cl1- is bonded in a trigonal non-coplanar geometry to three O2- atoms.

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36 MATERIALS SCIENCEBr-Cl-Co-H-N-OCoH18Br2N6ClO3crystal structure

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2020-04-29. Materials Data on CoH18Br2N6ClO3 by Materials Project. https://doi.org/10.17188/1725356

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