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DOE OSTI · 1726462

Materials Data on K2RbLuCl6 by Materials Project

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Abstract

(K)2RbLuCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight potassium molecules and one RbLuCl6 framework. In the RbLuCl6 framework, Rb1+ is bonded to six equivalent Cl1- atoms to form RbCl6 octahedra that share corners with six equivalent LuCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Rb–Cl bond lengths are 3.10 Å. Lu3+ is bonded to six equivalent Cl1- atoms to form LuCl6 octahedra that share corners with six equivalent RbCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Lu–Cl bond lengths are 2.58 Å. Cl1- is bonded in a linear geometry to one Rb1+ and one Lu3+ atom.

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36 MATERIALS SCIENCECl-K-Lu-Rbcrystal structureK2RbLuCl6

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2020-05-03. Materials Data on K2RbLuCl6 by Materials Project. https://doi.org/10.17188/1726462

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