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DOE OSTI · 1729090

Materials Data on AgMoH4S4N by Materials Project

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Abstract

MoAgS4NH4 is I4/mcm-derived structured and crystallizes in the tetragonal I-4 space group. The structure is one-dimensional and consists of two ammonium molecules and two MoAgS4 ribbons oriented in the (0, 0, 1) direction. In each MoAgS4 ribbon, Mo6+ is bonded to four equivalent S2- atoms to form MoS4 tetrahedra that share edges with two equivalent AgS4 tetrahedra. All Mo–S bond lengths are 2.22 Å. Ag1+ is bonded to four equivalent S2- atoms to form distorted AgS4 tetrahedra that share edges with two equivalent MoS4 tetrahedra. All Ag–S bond lengths are 2.55 Å. S2- is bonded in a 2-coordinate geometry to one Mo6+ and one Ag1+ atom.

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36 MATERIALS SCIENCEAg-H-Mo-N-SAgMoH4S4Ncrystal structure

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2020-05-03. Materials Data on AgMoH4S4N by Materials Project. https://doi.org/10.17188/1729090

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