Materials Data on Eu2Mo2O7 by Materials Project

Abstract

Eu2Mo2O7 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Eu+2.50+ is bonded to eight O2- atoms to form distorted EuO8 hexagonal bipyramids that share edges with six equivalent EuO8 hexagonal bipyramids and edges with six equivalent MoO6 octahedra. There are two shorter (2.29 Å) and six longer (2.62 Å) Eu–O bond lengths. Mo+4.50+ is bonded to six equivalent O2- atoms to form MoO6 octahedra that share corners with six equivalent MoO6 octahedra and edges with six equivalent EuO8 hexagonal bipyramids. The corner-sharing octahedral tilt angles are 46°. All Mo–O bond lengths are 2.03 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Eu+2.50+ atoms to form corner-sharing OEu4 tetrahedra. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Eu+2.50+ and two equivalent Mo+4.50+ atoms.