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DOE OSTI · 1730307

Materials Data on PtN2(ClO)2 by Materials Project

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Abstract

PtN2(OCl)2 crystallizes in the tetragonal P4_2/n space group. The structure is one-dimensional and consists of four PtN2(OCl)2 ribbons oriented in the (0, 1, 0) direction. Pt4+ is bonded in a distorted trigonal pyramidal geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Pt–O bond lengths are 2.02 Å. Both Pt–Cl bond lengths are 2.29 Å. N1+ is bonded in an L-shaped geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.55 Å. O2- is bonded in a distorted trigonal planar geometry to one Pt4+ and two equivalent N1+ atoms. Cl1- is bonded in a single-bond geometry to one Pt4+ atom.

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36 MATERIALS SCIENCECl-N-O-Ptcrystal structurePtN2(ClO)2

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2020-05-02. Materials Data on PtN2(ClO)2 by Materials Project. https://doi.org/10.17188/1730307

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