Materials Data on NiSb2H12(O3F4)2 by Materials Project

Abstract

Ni(H2O)6(SbF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two nsvfpfuroxfzjs-uhfffaoysa-n molecules and two SbF4 ribbons oriented in the (0, 0, 1) direction. In each SbF4 ribbon, Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.96–2.68 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.