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DOE OSTI · 1732569

Materials Data on AlH12C4NF4 by Materials Project

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Abstract

N(CH3)4AlF4 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one tetramethylammonium molecule and one AlF4 cluster. In the AlF4 cluster, Al3+ is bonded in a tetrahedral geometry to four F1- atoms. All Al–F bond lengths are 1.70 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Al3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Al3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Al3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Al3+ atom.

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36 MATERIALS SCIENCEAl-C-F-H-NAlH12C4NF4crystal structure

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2020-05-02. Materials Data on AlH12C4NF4 by Materials Project. https://doi.org/10.17188/1732569

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