Materials Data on SbSO2F7 by Materials Project

Abstract

SbF5SO2F2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules and four SbF5 clusters. In each SbF5 cluster, Sb5+ is bonded in a distorted trigonal bipyramidal geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.87–1.90 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.