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DOE OSTI · 1733781

Materials Data on PtBr3N2 by Materials Project

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Abstract

PtN2Br3 is Indium structured and crystallizes in the orthorhombic Imm2 space group. The structure is zero-dimensional and consists of two PtN2Br3 clusters. Pt5+ is bonded in a distorted trigonal bipyramidal geometry to two equivalent N1- and three Br1- atoms. Both Pt–N bond lengths are 1.77 Å. There are one shorter (2.41 Å) and two longer (2.57 Å) Pt–Br bond lengths. N1- is bonded in a single-bond geometry to one Pt5+ atom. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Pt5+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Pt5+ atom.

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36 MATERIALS SCIENCEBr-N-Ptcrystal structurePtBr3N2

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2020-05-02. Materials Data on PtBr3N2 by Materials Project. https://doi.org/10.17188/1733781

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