DOE OSTI · 1735151
Method of converting ethanol to higher alcohols
Abstract
A method and catalyst for forming higher alcohols from lower alcohol feedstocks. In one application a highly selective and stable copper pseudo-single-atom supported on MgO—Al2O3 catalyst is provided which provides ethanol condensation to higher alcohols at ˜50% yields and ˜85% selectivity is demonstrated with stable catalyst lifetime over 500 hours in a continuous flow system. In some applications a Guerbet condensation process is further utilized to yield a higher alcohol at a selectivity of near ˜90%.
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Ramasamy, Karthikeyan Kallupalayam, Guo, Mond F., Gray, Michel J., Subramaniam, Senthil. 2020-08-18. Method of converting ethanol to higher alcohols. https://www.osti.gov/biblio/1735151
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