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DOE OSTI · 1736371

Materials Data on NbRh2 by Materials Project

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Abstract

NbRh2 crystallizes in the monoclinic P2/m space group. The structure is three-dimensional. Nb is bonded in a 12-coordinate geometry to nine Rh atoms. There are a spread of Nb–Rh bond distances ranging from 2.74–2.80 Å. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded to six equivalent Nb atoms to form a mixture of distorted corner, edge, and face-sharing RhNb6 cuboctahedra. In the second Rh site, Rh is bonded to four equivalent Nb atoms to form a mixture of distorted corner and edge-sharing RhNb4 cuboctahedra. In the third Rh site, Rh is bonded in a distorted linear geometry to two equivalent Nb atoms.

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36 MATERIALS SCIENCEcrystal structureNb-RhNbRh2

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2020-05-02. Materials Data on NbRh2 by Materials Project. https://doi.org/10.17188/1736371

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