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DOE OSTI · 1738531

Materials Data on ClO5 by Materials Project

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Abstract

O2(ClO4)2 is Silicon tetrafluoride-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four water molecules and four ClO4 clusters. In each ClO4 cluster, there are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.44 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.45 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.48 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

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36 MATERIALS SCIENCECl-OClO5crystal structure

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2020-05-03. Materials Data on ClO5 by Materials Project. https://doi.org/10.17188/1738531

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