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DOE OSTI · 1738839

Materials Data on RuSN4(ClO)2 by Materials Project

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Abstract

RuN2ClN2ClSO2 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four sulfur dioxide molecules, four N2Cl clusters, and four RuN2Cl clusters. In each N2Cl cluster, N1+ is bonded in a single-bond geometry to one Cl1- atom. The N–Cl bond length is 1.53 Å. Cl1- is bonded in a 2-coordinate geometry to two equivalent N1+ atoms. In each RuN2Cl cluster, Ru4+ is bonded in a trigonal non-coplanar geometry to two equivalent N1+ and one Cl1- atom. Both Ru–N bond lengths are 1.72 Å. The Ru–Cl bond length is 2.26 Å. N1+ is bonded in a single-bond geometry to one Ru4+ atom. Cl1- is bonded in a single-bond geometry to one Ru4+ atom.

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36 MATERIALS SCIENCECl-N-O-Ru-Scrystal structureRuSN4(ClO)2

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2020-04-29. Materials Data on RuSN4(ClO)2 by Materials Project. https://doi.org/10.17188/1738839

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