Materials Data on Tc3Mo by Materials Project

Abstract

MoTc3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Mo5+ is bonded to twelve equivalent Tc+1.67- atoms to form MoTc12 cuboctahedra that share corners with twelve equivalent MoTc12 cuboctahedra, edges with twenty-four equivalent TcTc8Mo4 cuboctahedra, faces with six equivalent MoTc12 cuboctahedra, and faces with twelve equivalent TcTc8Mo4 cuboctahedra. All Mo–Tc bond lengths are 2.77 Å. Tc+1.67- is bonded to four equivalent Mo5+ and eight equivalent Tc+1.67- atoms to form TcTc8Mo4 cuboctahedra that share corners with twelve equivalent TcTc8Mo4 cuboctahedra, edges with eight equivalent MoTc12 cuboctahedra, edges with sixteen equivalent TcTc8Mo4 cuboctahedra, faces with four equivalent MoTc12 cuboctahedra, and faces with fourteen equivalent TcTc8Mo4 cuboctahedra. All Tc–Tc bond lengths are 2.77 Å.