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DOE OSTI · 1741513

Materials Data on Sb(Cl2O)3 by Materials Project

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Abstract

(SbCl6)2(O2)3 is Modderite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and four SbCl6 clusters. In each SbCl6 cluster, Sb is bonded in an octahedral geometry to six Cl atoms. There are a spread of Sb–Cl bond distances ranging from 2.39–2.41 Å. There are six inequivalent Cl sites. In the first Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the second Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the third Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the fourth Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the fifth Cl site, Cl is bonded in a single-bond geometry to one Sb atom. In the sixth Cl site, Cl is bonded in a single-bond geometry to one Sb atom.

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36 MATERIALS SCIENCECl-O-Sbcrystal structureSb(Cl2O)3

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2020-05-02. Materials Data on Sb(Cl2O)3 by Materials Project. https://doi.org/10.17188/1741513

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36 MATERIALS SCIENCE↗