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DOE OSTI · 1742162

Materials Data on Ni(ClO3)2 by Materials Project

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Abstract

Ni(O3Cl)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two Ni(O3Cl)2 ribbons oriented in the (0, 1, 0) direction. Ni is bonded in a distorted octahedral geometry to four equivalent O and two equivalent Cl atoms. All Ni–O bond lengths are 2.09 Å. Both Ni–Cl bond lengths are 2.50 Å. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to two equivalent O atoms. Both O–O bond lengths are 1.34 Å. In the second O site, O is bonded in a water-like geometry to one Ni and one O atom. Cl is bonded in a distorted single-bond geometry to one Ni atom.

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36 MATERIALS SCIENCECl-Ni-Ocrystal structureNi(ClO3)2

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2020-05-02. Materials Data on Ni(ClO3)2 by Materials Project. https://doi.org/10.17188/1742162

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