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DOE OSTI · 1743388

Materials Data on CoN4Cl2O3 by Materials Project

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Abstract

CoNOCl(NO)2NCl crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two chloramine molecules, four nitroxyl molecules, and one CoNOCl cluster. In the CoNOCl cluster, Co4+ is bonded in a 3-coordinate geometry to one N1+ and two equivalent O2- atoms. The Co–N bond length is 1.69 Å. There is one shorter (1.74 Å) and one longer (1.86 Å) Co–O bond length. N1+ is bonded in a distorted bent 120 degrees geometry to one Co4+ and one Cl1- atom. The N–Cl bond length is 1.65 Å. O2- is bonded in a water-like geometry to two equivalent Co4+ atoms. Cl1- is bonded in a single-bond geometry to one N1+ atom.

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36 MATERIALS SCIENCECl-Co-N-OCoN4Cl2O3crystal structure

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2020-05-03. Materials Data on CoN4Cl2O3 by Materials Project. https://doi.org/10.17188/1743388

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