Materials Data on K2Mo(SO)2 by Materials Project

Abstract

K2Mo(SO)2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. K1+ is bonded in a 3-coordinate geometry to five equivalent S2- and three equivalent O2- atoms. There are a spread of K–S bond distances ranging from 3.35–3.66 Å. There are a spread of K–O bond distances ranging from 2.82–2.95 Å. Mo6+ is bonded in a tetrahedral geometry to two equivalent S2- and two equivalent O2- atoms. Both Mo–S bond lengths are 2.24 Å. Both Mo–O bond lengths are 1.79 Å. S2- is bonded in a 1-coordinate geometry to five equivalent K1+ and one Mo6+ atom. O2- is bonded in a 4-coordinate geometry to three equivalent K1+ and one Mo6+ atom.