Materials Data on TmInCo4 by Materials Project

Abstract

TmCo4In crystallizes in the cubic F-43m space group. The structure is three-dimensional. Tm is bonded in a 12-coordinate geometry to twelve equivalent Co and four equivalent In atoms. All Tm–Co bond lengths are 2.91 Å. All Tm–In bond lengths are 3.04 Å. Co is bonded to three equivalent Tm, six equivalent Co, and three equivalent In atoms to form a mixture of edge, face, and corner-sharing CoTm3In3Co6 cuboctahedra. There are three shorter (2.47 Å) and three longer (2.49 Å) Co–Co bond lengths. All Co–In bond lengths are 2.91 Å. In is bonded in a 4-coordinate geometry to four equivalent Tm and twelve equivalent Co atoms.