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DOE OSTI · 1747393

Materials Data on Ni(SO6)2 by Materials Project

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Abstract

NiO6(SO3)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one NiO6 cluster. In the NiO6 cluster, Ni is bonded in a square co-planar geometry to four O atoms. There is two shorter (1.63 Å) and two longer (2.15 Å) Ni–O bond length. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one O atom. The O–O bond length is 1.24 Å. In the second O site, O is bonded in a single-bond geometry to one Ni atom. In the third O site, O is bonded in a bent 120 degrees geometry to one Ni and one O atom.

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36 MATERIALS SCIENCEcrystal structureNi(SO6)2Ni-O-S

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2020-05-02. Materials Data on Ni(SO6)2 by Materials Project. https://doi.org/10.17188/1747393

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