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DOE OSTI · 1747431

Materials Data on Zn2SnO4 by Materials Project

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Abstract

Zn2SnO4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Zn2+ is bonded to six equivalent O2- atoms to form ZnO6 octahedra that share corners with six equivalent SnO4 tetrahedra and edges with six equivalent ZnO6 octahedra. All Zn–O bond lengths are 2.13 Å. Sn4+ is bonded to four equivalent O2- atoms to form SnO4 tetrahedra that share corners with twelve equivalent ZnO6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Sn–O bond lengths are 2.00 Å. O2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Zn2+ and one Sn4+ atom.

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36 MATERIALS SCIENCEcrystal structureO-Sn-ZnZn2SnO4

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2020-05-02. Materials Data on Zn2SnO4 by Materials Project. https://doi.org/10.17188/1747431

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