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DOE OSTI · 1748173

Materials Data on Ge2RuC4(Cl3O2)2 by Materials Project

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Abstract

Ru(CO)4(GeCl3)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trichlorogermane molecules and two Ru(CO)4 clusters. In each Ru(CO)4 cluster, Ru6+ is bonded in a square co-planar geometry to four equivalent C atoms. There is two shorter (1.97 Å) and two longer (1.98 Å) Ru–C bond length. C is bonded in a linear geometry to one Ru6+ and one O2- atom. The C–O bond length is 1.15 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C atom. The O–C bond length is 1.15 Å.

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36 MATERIALS SCIENCEC-Cl-Ge-O-Rucrystal structureGe2RuC4(Cl3O2)2

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2020-05-02. Materials Data on Ge2RuC4(Cl3O2)2 by Materials Project. https://doi.org/10.17188/1748173

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