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DOE OSTI · 1753448

Materials Data on WO5 by Materials Project

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Abstract

WO5 crystallizes in the monoclinic P2_1 space group. The structure is one-dimensional and consists of four hydrogen peroxide molecules and two WO3 ribbons oriented in the (0, 1, 0) direction. In each WO3 ribbon, W is bonded in a 5-coordinate geometry to five O atoms. There are a spread of W–O bond distances ranging from 1.73–2.18 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to three equivalent W atoms. In the second O site, O is bonded in a single-bond geometry to one W atom. In the third O site, O is bonded in a single-bond geometry to one W atom.

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36 MATERIALS SCIENCEcrystal structureO-WWO5

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2020-05-02. Materials Data on WO5 by Materials Project. https://doi.org/10.17188/1753448

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