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DOE OSTI · 1758669

Materials Data on Na6WN4 by Materials Project

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Abstract

Na6WN4 crystallizes in the tetragonal P4_2/nmc space group. The structure is three-dimensional. there are two inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded in a 4-coordinate geometry to four equivalent N3- atoms. There are two shorter (2.40 Å) and two longer (2.81 Å) Na–N bond lengths. In the second Na1+ site, Na1+ is bonded in a 4-coordinate geometry to four equivalent N3- atoms. There are two shorter (2.44 Å) and two longer (2.51 Å) Na–N bond lengths. W6+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All W–N bond lengths are 1.92 Å. N3- is bonded in a 7-coordinate geometry to six Na1+ and one W6+ atom.

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36 MATERIALS SCIENCEcrystal structureN-Na-WNa6WN4

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2020-09-03. Materials Data on Na6WN4 by Materials Project. https://doi.org/10.17188/1758669

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